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CE–MS is increasingly gaining momentum as an analytical tool in metabolomics, due to its ability to obtain information about the most polar elements in biological samples. This has been helped by improvements of robustness in peak identification by means of mobility‐scale representations of the electropherograms (mobilograms). As a necessary step toward facilitating the use of CE–MS for untargeted...
The use of capillary electrophoresis coupled to mass spectrometry (CE‐MS) in metabolomics remains an oddity compared to the widely adopted use of liquid chromatography. This technique is traditionally regarded as lacking the reproducibility to adequately identify metabolites by their migration times. The major reason is the variability of the velocity of the background electrolyte, mainly coming from...
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