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Microstructure Design
In article number 2203229, Shikuan Yang and co‐workers propose an avenue to regulate the morphologies of the electrodeposits during the anodic electrodeposition process by introducing the intermediate valence ions (e.g., Pb2+, Mn2+, etc.) into the electrolyte solutions. The intermediate valence ions could react with the electrochemically oxidized Ag2+/Ag3+ ions with strong oxidation...
The assembly of biomolecules and ions (e.g., biomineralization process) generates many intricate structures in nature. However, human beings’ control over the assembly processes of ions is in its infant stage compared with nature. Here, it is reported that the intermediate valence metal ions in the electrolyte can influence the growth speed of certain crystal facets and in turn adjust the shape of...
Microarchitectures with complex interior structures are important for many applications. However, engineering complex interior structures within microarchitectures are challenging. This article reports the introduction of electrochemical sculpting processes to carve the microarchitectures during or after their electrochemical growing process to design the interior structure of the microarchitectures...
Shape‐ and size‐controlled synthesis of micro/nanostructures is of fundamental importance in many applications of physics and chemistry. Wet chemical growth methods have achieved shape‐ and size‐controlled synthesis of colloidal nanocrystals of various compositions. Compared with wet chemical methods, electrochemical deposition (ECD) yields micro/nanostructures affixed to a substrate, but the resulting...
The controllable electrochemical fabrication of well‐defined silver‐oxide clathrate micro‐/nanostructures is realized by Shikuan Yang and co‐workers in article number 1805686 by intentionally manipulating the previously neglected electrocarving process during electrodeposition growth (MEDEG). The dominance of the electrocarving and the electrodeposition growth process can be immediately manipulated...
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