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Nitrate was used as a promoter to prepare dodecyltrimethoxysilane thin films on aluminum substrates. With the addition of nitrate into silane sol–gel precursors, the electro-assisted formation of silane films was facilitated, as indicated by electrochemical impedance spectroscopy, scanning electron microscopy and secondary-ion mass spectroscopy, due to the promotion in cathodic alkalization. However,...
Novel silane/TiO 2 bifunctional hybrid films based on highly protective bis-[triethoxysilylpropyl]-tetrasulfide silane were prepared on stainless steel substrates. With the addition of silane agent, TiO 2 particles can be more easily immobilized and better dispersed onto the substrates, leading to significant enhancement of the photocathodic protection to substrates under ultraviolet...
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