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The structure evolution and surface modification of the ZnSb, ZnSb-Bi and ZnSb-NiO phase-change films are detected by in situ Raman laser irradiation with the different laser power and irradiation time. The results show that undoped ZnSb films exhibit a phase transformation from amorphous to metastable phases at 250 mW. The Bi-doped ZnSb films exhibit two different crystallization behaviors as the...
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