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Two newly designed fluorescent complexes, [Zn(L)(MeOH)]·CH2Cl2 (1) and [{NiL(MeOH)(μ-OAc)}2Ni]·4CH2Cl2 (2) based on a coumarin-containing N2O2 chelating ligand H2L have been synthesized and characterized by elemental analyses, IR and UV–Vis spectra, fluorescence spectra and X-ray crystallography. Complex 1 includes one Zn(II) atom, one completely deprotonated (L)2− unit, one coordinated methanol molecule...
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