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Solar‐to‐fuel conversion with organic–inorganic hybrid halide perovskites has attracted growing attention as a result of their excellent optoelectronic properties as well as the low temperature of the solution based fabrication process. However, the most comprehensively developed hybrid perovskite materials are comprised of the toxic metal lead, raising concerns about environmental health threats...
In article number 2006919, Hsien‐Yi Hsu and co‐workers report a feasible solvent‐engineering technique for in‐situ formation of a lead‐free bismuth (Bi)‐based perovskite heterostructure for high‐performance co‐catalyst‐free photocatalytic hydrogen generation. Driven by energy band alignment across the interface of a phase junction, the air‐stable MA3Bi2I9/DMA3BiI6 perovskite heterostructure exhibits...
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