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Electrophilic additions of HCl to a series of asymmetric alkenes in the gas phase have been investigated in the light of the ABEEM-σπ model and high-level ab initio method. We demonstrated well the regioselectivity of the electrophilic reactions by means of the ABEEM-σπ model on the basis of local HSAB principle and maximum hardness principle. According to the charge distribution in the initial state...
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