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In this article, Polynorbornene (PNB)/Zinc dimethacrylate (ZDMA)/Dicumyl peroxide (DCP) composites can form dual‐crosslinking networks, which contain an ionic crosslinking network, and a part of the C─C covalent crosslinking network. DCP was used to initiate the polymerization of ZDMA to form ionic crosslinking bonds. With the increase of ZDMA, the total crosslink density (Vr) and ionic crosslink...
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