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This research established a non-labeled electrochemical biosensor for discrimination of recombinant human erythropoietin (rhEPO) and endogenous erythropoietin (EPO). We prepared a glassy carbon electrode (GCE) modified by a unique sandwich-like nano-Au/ZnO sol–gel/nano-Au compound membrane for signal amplification. The porous sol–gel structure facilitates protein activity maintenance and thermostability...
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