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The processing–structure–property relationship using poly(lactic acid) (PLA) and poly(ethylene terephthalate) (PET) is explored. Specifically, both pre‐extension and preshear of amorphous PLA and PET above their glass transition temperatures Tg, carried out in the affine deformation limit, can induce a specific type of cold crystallization during annealing, i.e., nanoconfined crystallization (NCC)...
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