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Novel terpolymers with furan and maleimide units as functional moieties for the reversible crosslinking by the Diels–Alder (DA) reaction with different polar and nonpolar co-monomers and linkers have been prepared for potential applications as self-healing coatings. The synthesized linear one-component systems are able to crosslink via the functional units in the side chain (i.e. furan and maleimide)...
Histidine-metal interactions are utilized in many biological materials as reinforcing crosslinks, and in particular, are believed to contribute as reversible crosslinks to the intrinsic self-recovery behavior of mussel byssal threads. In this contribution, two new histidine-based monomers were synthesized and further copolymerized with butyl methacrylate (BMA) and lauryl methacrylate (LMA) applying...
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