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Surprising new results were obtained during our investigations on the thermooxidative degradation of poly(vinyl chloride) (PVC) in dioctyl phthalate, DOP (bis(2-ethylhexyl) phthalate, DEHP), at 200 °C, i.e., in the range of the processing temperature of PVC. Enhanced dehydrochlorination of the polymer was found in DOP on the one hand. It is a striking observation that oily products are formed after...
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