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The orientations of halobenzenes (C 6 H 5 Cl and C 6 H 5 I) and phenyl (C 6 H 5 ) groups adsorbed on a Cu(111) surface have been studied by the near edge X-ray absorption fine structure (NEXAFS) method. For near-monolayer coverages, both chlorobenzene (C 6 H 5 Cl) and iodobenzene (C 6 H 5 I) bond with the plane of their...
The chemisorption and decomposition of tris(dimethylamino) phosphine (DMAP) on GaAs(100) are investigated with temperature-programmed reaction spectroscopy (TPR) and D atom coadsorption experiments. Below monolayer coverage, the majority of DMAP molecules adsorbed at 120 K dissociates at elevated temperatures. At higher surface coverages, DMAP desorbs molecularly with a desorption peak temperature...
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