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Potassium promoted molybdenum sulfide catalysts are well-known for the conversion of synthesis gas (H2 and CO) to higher alcohols, primarily ethanol and propanol. Basic supports composed of mixed MgAl based oxides from decomposed hydrotalcites are known to yield enhanced higher alcohol selectivities compared to bulk or carbon supported molybdenum sulfide catalysts. In this study, the role of the metal...
A Mg/Al mixed metal oxide material (MMO) is introduced as a support for K2CO3 promoted MoS2 in CO hydrogenation reactions at 310 °C and 1,500 psig. The catalyst is shown to be more selective for C2–C4 linear alcohols (substantially so for C3–C4 linear alcohols) than for methanol and offers good alcohol to hydrocarbon selectivity. Methanol selectivity of the MMO supported catalyst deviates greatly...
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