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Proton‐conductive metal‐organic frameworks (MOFs) have attracted great attention for their promising application in membrane fuel cells. To explore proton‐conductive MOFs with high performance, here we present four lanthanide‐hypophosphite frameworks with distinct amine guests. These complexes possess a general formula [AH][Gd2(H2PO2)7] (AH = protonated amines). Due to the rich hydrogen bond networks,...
A series of heterometallic 3d–Gd3+ complexes based on a lanthanide metalloligand, [M(H2O)6][Gd(oda)3]⋅3 H2O [M=Cr3+ (1‐Cr)] (H2oda=2,2′‐oxydiacetic acid), [M(H2O)6][MGd(oda)3]2⋅3 H2O [M=Mn2+ (2‐Mn), Fe2+ (2‐Fe) and Co2+ (2‐Co)], and [M3Gd2(oda)6(H2O)6]⋅12 H2O [M=Ni2+ (3‐Ni), Cu2+ (3‐Cu), and Zn2+ (3‐Zn)], are reported. Magnetic and heat‐capacity studies revealed a significant impact on the magnetocaloric...
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