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It is an obstacle to precisely manipulate a doped heteroatom into a desired position in a metal nanocluster. Herein, we overcome this difficulty to obtain Pt1Au37(SCH2PhtBu)24 and Pt2Au36(SCH2PhtBu)24 nanoclusters via controllably doping Pt atoms into the kernels of Au38(SCH2PhtBu)24. We reveal that asymmetrical doping of one Pt atom into either of the cores of Au38(SCH2PhtBu)24 elevates the relative...
It is an obstacle to precisely manipulate a doped heteroatom into a desired position in a metal nanocluster. Herein, we overcome this difficulty to obtain Pt1Au37(SCH2PhtBu)24 and Pt2Au36(SCH2PhtBu)24 nanoclusters via controllably doping Pt atoms into the kernels of Au38(SCH2PhtBu)24. We reveal that asymmetrical doping of one Pt atom into either of the cores of Au38(SCH2PhtBu)24 elevates the relative...
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