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The synthesis and properties of a solvent-free gel polymer electrolyte based on an imidazolium-poly(ethylene oxide) (PEO)-based ionene electrolyte, a poly(vinylidene fluoride-hexafluoropropylene) (PVDF(HFP)) support, and the lithium bis(trifluoromethane sulfonyl) imide (LiTFSI) salt are reported. A ternary gel polymer electrolyte film, produced from mixtures of the imidazolium-PEO-based ionene ([IPI][Br]),...
Nylon 4/6 copolymers based on 2-pyrrolidone (C4) and ε-caprolactam (C6) were synthesized and characterized as part of ongoing efforts to develop thermally stable, melt-processable 2-pyrrolidone (C4) based Nylons. Copolymers of various compositions were synthesized at between 50 and 100 °C via the anionic ring opening polymerization of C4 and C6 using a potassium tert-butoxide catalyst and a benzoyl...
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