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We annealed Ge–Sb–S–CsCl glass and investigated the evolution of the structural, optical and mechanical properties as a function of annealing temperature. It was found that, for the glass annealed at 280 °C for 210 h, a CsCl crystalline phase with mono-dispersedly spherical shape was formed; while for the glass annealed at 370 °C for 5 h, both β-GeS 2 and CsCl crystalline phases with irregular...
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