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The construction of stable copper nanoclusters (Cu‐NCs) with near‐infrared (NIR) emission that can be used for catalysis is highly desired, yet remains a challenge. Herein, an atomically precise bimetallic Cu/Pd NC with a molecular formula of Cu16Pd1L10(PPh3)2(Pz)6 (Pz = 3,5‐(CF3)2Pyrazolate, L = 4‐CH3OPhC≡C−), abbreviated as Cu16Pd1, is synthesized. Single‐crystal X‐ray crystallographic analysis...
Developing effective catalysts to degrade chemical warfare agents is of great significance. Herein, a mesoporous MIL‐101(Cr) composite material dangled with porphyrin molecules (denote as TCPP@MIL‐101(Cr), TCPP = tetra(4‐carboxyphenyl)porphyrin) is reported, which can be used as a heterogeneous photocatalyst for detoxification of mustard gas simulants 2‐chloroethyl ethyl sulfide (CEES) to 2‐chloroethyl...
For over a hundred years, X‐rays have been a main component of the radiotherapeutic approaches to treat cancer. Yet, to date, no radiosensitizer has been developed to selectively target prostate cancer. Gold has excellent X‐ray absorptivity and is used as a radiotherapy enhancing material. In this work, ultrasmall Au25 nanoclusters (NCs) are developed for selective prostate cancer targeting, radiotherapy...
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