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A comprehensive study on various internal energies, pressures and chemical potentials for the pure dipolar hard sphere fluids, pure Stockmayer fluids, the Lennard-Jones and Stockmayer mixtures, the Stockmayer and Stockmayer mixtures and the ion-dipole mixtures is reported based on the perturbation theory (PT) and mean spherical approximation (MSA). Compared with the results of molecular simulations,...
Based on perturbation theory, a new equation of state is developed for real electrolyte aqueous fluids, which is composed of ion-ion, ion-dipole, dipole-dipole, Lennard-Jones dispersion, hydrogen bonding association and hard sphere repulsion terms. The MSA equation from Blum is adopted instead of the perturbed electrostatic term, which simplifies the calculation. The SAFT equation is adopted for the...
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