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The electrochemical reductive coupling of 2-cyclohexen-1-one in a mixture of 1-butyl-3-methylimidazolium tetrafluoroborate ionic liquid with water afforded the 1,6-diketone (1,1′-bicyclohexyl)-3,3′-dione in 90% yield at room temperature via regioselective coupling at the β-carbon. The addition of water was necessary to increase the conductivity of the ionic liquid. The method provides a green electrolytic...
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