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Lithium–air (Li–air) batteries stand out among the post‐Li‐ion batteries due to their high energy density, which has rapidly progressed in the past years. Regarding the fundamental mechanism of Li–air batteries that discharge products produced and decomposed during charging and recharging progress, the reversibility of products closely affects the battery performance. Along with the upsurge of the...
Surface discharge mechanism induced cathode passivation is a critical challenge that blocks the full liberation of the ultrahigh theoretical energy density in aprotic Li–O2 batteries. Herein, a facile and universal concept of hydrogen‐bond‐assisted solvation is proposed to trigger the solution discharge process for averting the shortcomings associated with surface discharge. 2,5‐Di‐tert‐butylhydroquinone...
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