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Yellowish-orange-emitting ZnGeN 2 and orange-red-emitting ZnGeN 2 :Mn were synthesized by a facile and mild gas-reduction–nitridation reaction at 1153K under NH 3 flow with air-stable raw materials ZnO, GeO 2 and MnCO 3 . The structure, composition, morphology, photoluminescence and cathodoluminescence properties of ZnGeN 2 doped with or without Mn ...
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