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When the MBT−:Cl− ratio is 50–10:1 in a solution containing of NaCl and Na-MBT (sodium salt of 2-mercaptobenzothiazole), the copper sample-1 (S1) was passivated; when the ration is 10–5:1, it was corroded. The copper sample-2 (S2) had no anti-corrosive ability in all solutions with MBT−:Cl−=50–5:1. First-principle calculation revealed that the Cu atoms of (220) face, the main face of S1, have more...
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