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Changes in atomic bonding configuration in carbon from sp3 to sp2 are known to exist in certain structural defects in diamond, such as twin boundaries, grain boundaries, and dislocations, which have a significant impact on many properties of diamond. In this work, the atomic structure of fivefold twinning in detonation synthesized ultra‐dispersed diamonds is investigated using a combination of techniques,...
Diamonds
In article number 2302914, Lu‐Chang Qin and co‐workers propose a new extended core structure with co‐hybridization of sp2‐ and sp3‐bonding of carbon and analyze it for the fivefold twinning centers of diamond using a combination of techniques of high‐resolution electron microscopy, image simulations, and molecular mechanics calculations.
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