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Li2CO3‐passivated Li3N with high stability is prepared by aging Li3N powder in dry air, and is then used as an electrode additive for a Li(Li0.18Ni0.15Co0.15Mn0.52)O2 (LLMO) cathode material. The material shows a large irreversible capacity of 800 mA h g−1 during the first charge, with the formation of a Li2N intermediate product. Acting as a Li+ sacrificial salt for a LLMO(+)/graphite(−) Li‐ion battery,...
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