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Je nach M+ verhalten sich die Hydride des H2Cu11‐Reaktanten unterschiedlich. Im Falle von M=Cu oder Ag wirken sie als reguläre 2‐Elektronen‐Liganden und bilden [CuH2Cu11{S2P(OiPr)2}6(C≡CPh)3]+ (Cu12H2), [AgH2Cu14{S2P(OiPr)2}6(C≡CPh)6]+ (AgH2Cu14); im Fall von M=Au verhalten sie sich als Elektronendonoren und bilden [AuCu11{S2P(OiPr)2}6(C≡CPh)3Cl] (AuCu11). Einzelheiten der Studie stellen Jean‐Yves...
In sharp contrast to surface hydrides, reactivities of interstitial hydrides are difficult to explore. When treated with a metal ion (Cu+, Ag+, and Au+), the stable CuI dihydride template [Cu11H2{S2P(OiPr)2}6(C≡CPh)3] (H2Cu11) generates surprisingly three very different compounds, namely [CuH2Cu11{S2P(OiPr)2}6(C≡CPh)3]+ (1), [AgH2Cu14{S2P(OiPr)2}6((C≡CPh)6]+ (2), and [AuCu11{S2P(OiPr)2}6(C≡CPh)3Cl]...
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