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The separation of ethylene (C2H4) from a mixture of ethane (C2H6), ethylene (C2H4), and acetylene (C2H2) at normal temperature and pressure is a significant challenge. The sieving effect of pores is powerless due to the similar molecular size and kinetic diameter of these molecules. We report a new modification method based on a stable ftw topological Zr‐MOF platform (MOF‐525). Introduction of a cyclopentadiene...
Eine CpCo‐Einheit wurde in einen kubischen Käfig eingeführt, um eine sphärische Kraftfläche zu erzeugen, wodurch der kubische Käfig in zwei Teile geteilt wird. Gasmoleküle müssen die sphärische Kraftfläche zweimal passieren, was die Wechselwirkungswahrscheinlichkeit zwischen Gas und Gerüst erhöht. Aufgrund der hohen Selektivität der CpCo‐Gruppe wird hochreines Ethylen aus einem ternären Acetylen/Ethylen/Ethan‐Gemisch...
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