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Nickel complexes with a two‐electron reduced CO2 ligand (CO22−, “carbonite”) are investigated with regard to the influence alkali metal (AM) ions have as Lewis acids on the activation of the CO2 entity. For this purpose complexes with NiII(CO2)AM (AM=Li, Na, K) moieties were accessed via deprotonation of nickel‐formate compounds with (AM)N(iPr)2. It was found that not only the nature of the AM ions...