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The formation of hybrid silica‐based systems to study the effect of the confinement on the emission properties of self‐assembled platinum(II) complexes is reported. The complexes behave as surfactants since they possess a hydrophobic moiety and, on the ancillary ligand, a relatively long hydrophilic chain terminated with a positively charged group. The compounds, soluble in water, self‐assemble, even...
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