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Methanol‐to‐olefin (MTO) catalysis is a very active field of research because there is a wide variety of sometimes conflicting mechanistic proposals. An example is the ongoing discussion on the initial C−C bond formation from methanol during the induction period of the MTO process. By employing a combination of solid‐state NMR spectroscopy with UV/Vis diffuse reflectance spectroscopy and mass spectrometry...
Der Reaktionsmechanismus der industriell wichtigen Umwandlung von Methanol in Olefine über Zeolithkatalysatoren wurde untersucht. In der Zuschrift auf S. 16072 ff. zeigen M. Baldus, B. M. Weckhuysen et al. einen effektiven, auf Festkörper‐NMR‐Spektroskopie und Operando‐UV/Vis‐Spektroskopie basierenden Ansatz, um den Beweis für einen direkten Mechanismus bei der Bildung der ersten Kohlenstoff‐Kohlenstoff‐Bindung...
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