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Interface engineering is a critical method by which to efficiently enhance the photovoltaic performance of nonfullerene solar cells (NFSC). Herein, a series of metal–nanographene‐containing large transition metal involving dπ–pπ conjugated systems by way of the addition reactions of osmapentalynes and p‐diethynyl‐hexabenzocoronenes is reported. Conjugated extensions are engineered to optimize the...
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