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Amphiphilic comb-like copolymer consisting of a poly(vinyl chloride) (PVC) backbone and poly(styrene sulfonic acid) (PSSA) side chains, i.e. PVC-g-PSSA at 68:32 wt.% was synthesized via atom transfer radical polymerization (ATRP). This self-assembled graft copolymer film was used to template the growth of Ag–Au bimetallic nanoparticles in the solid state by introducing NaBH 4 as a reducing...
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