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CaZrO3 samples were prepared by in situ decomposition pore forming technology in this paper. The influence of calcia/zirconia molar ratio and heating treatment on the microstructure and thermal conductivity of the sintered samples were investigated. The phase analysis of CaZrO3 samples was detected by X‐ray diffraction, and the microscopic morphology of CaZrO3 was observed by scanning electron microscope...