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2‐Amino[2.2]paracyclophane reacts with salicylaldehyde or 2‐hydroxyacetophenone to yield imines that then give access to a new series of boranils (8b–d) upon complexation with BF2. These novel boron‐containing compounds display both planar and axial chiralities and were examined experimentally and computationally. In particular, their photophysical and chiroptical properties were studied and compared...
A new enantiopure cyclometallated iridium complex bearing a [4]helicenic
‐coordinating and two
‐coordinating dfppy (2‐(2,4‐difluorophenyl)‐pyridyl) ligands was prepared. This complex displayed long‐lived phosphorescence both in solution and in the solid state. Its chiroptical properties, namely electronic circular dichroism and circularly polarized luminescence, were also examined. Comparison...
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