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Eine mangankatalysierte Esterreduktion wird durch Abstimmen der Reaktivität der MnI‐Spezies mit einfachen zweizähnigen P,N‐Liganden und einer Alkoxidbase möglich. E. A. Pidko et al. stellen in ihrer Zuschrift auf S. 7639 ff. hochaktive Mn‐Katalysatoren für die selektive Esterhydrierung vor. Die Aktivität der Katalysatoren ist das Resultat einer feinen Balance zwischen den katalytischen und desaktivierenden...
Catalytic hydrogenation of carboxylic acid esters is essential for the green production of pharmaceuticals, fragrances, and fine chemicals. Herein, we report the efficient hydrogenation of esters with manganese catalysts based on simple bidentate aminophosphine ligands. Monoligated Mn PN complexes are particularly active for the conversion of esters into the corresponding alcohols at Mn concentrations...
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