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Die inhärenten Bindungspräferenzen von Alkalimetallen werden in den Strukturen von Corannulen‐Monoanionen, die mit Cs+‐ und Rb+‐Ionen in Gegenwart von [18]Krone‐6 kristallisiert wurden, offenbar, die zudem eine Einschätzung der Schalendeformation ermöglichen, die durch die Verteilung der negativen Ladung und die Metallbindung verursacht wird. Das große Cs+ wird ausschließlich von der konkaven Seite...
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