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Palladium nanoparticles stabilized by thioether-phosphine ligands (1–3) were used as catalytic precursors in Heck–Mizoroki cross-coupling and CC reduction reactions in ionic liquids. The ionic liquid [EMI][MeHPO 3 ] (A) exhibited an important hydrogen donor/acceptor behavior depending on the reaction conditions. Tandem or parallel pathways for C–C coupling and H-transfer reactions were observed,...
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