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The metabolic labeling of nucleic acids in living cells is highly desirable to track the dynamics of nucleic acid metabolism in real‐time and has the potential to provide novel insights into cellular biology as well as pathogen‐host interactions. Catalyst‐free inverse electron demand Diels–Alder reactions (iEDDA) with nucleosides carrying highly reactive moieties such as axial 2‐trans‐cyclooctene...
Das metabolische Labeling von Nucleinsäuren in lebenden Zellen ist von äußerstem Interesse, um die Dynamik des Nucleinsäure‐Stoffwechsels in Echtzeit zu verfolgen und hat somit das Potenzial, neue Einblicke in die Zellbiologie sowie in Pathogen‐Wirtszell‐Interaktionen zu liefern. Eine katalysatorfreie Diels–Alder‐Reaktion mit inversem Elektronenbedarf (iEDDA) mit Nucleosiden, die eine hochreaktive...