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The 0.74Na1/2Bi1/2TiO3–0.26SrTiO3 codoped with Li2CO3 and B2O3 is studied to develop the low‐temperature sintered lead‐free piezoceramic for multilayer applications. The studied piezoceramics are synthesized by a conventional solid‐state reaction method. Their crystal structures, microstructures, ferroelectrics, and strain properties are analyzed. Interestingly, the addition of Li2CO3 and B2O3 reduces...