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Amid‐Trittsteine: Zwischen den Enden α‐helicaler Peptide, die sich in selbstorganisierten Monoschichten (SAMs) auf einer Goldoberfläche befinden, findet ein Elektronenaustausch statt, wobei die Amidgruppen als Zentren für den Hüpfvorgang fungieren (siehe Bild). Die Geschwindigkeitskonstante von 0.45 s−1 für das 64‐mere Peptid ist ungewöhnlich hoch für einen Elektronentransfer durch ein organisches...
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