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Stibinyl and bismuthinyl radicals are recognized as representative intermediates of antimony and bismuth compounds, but still elusive in the condensed phase. We successfully synthesized persistent stibinyl and bismuthinyl radicals in solution by facile dissociation of the corresponding dimers with bulky substituents. We characterized the radicals by NMR and UV/Vis spectroscopy and estimated the thermodynamic...
Stabile Sb‐ und Bi‐Radikale Die Synthese und spektroskopische Charakterisierung stabiler Stibinyl‐ und Bismutinylradikale in Lösung wird von S. Ishida, T. Iwamoto et al. in ihrer Zuschrift auf S. 11354 ff. beschrieben.
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