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A novel approach has been proposed to enhance the flame retardancy of ABS by a highly efficient intumescent flame retardant coating, which was prepared by aluminum‐ ethylene glycol methyl propionate cyclohexanediol phosphonate (EMPCP‐Al), polyvinyl formal (PVFO) and melamine cyanurate with specific ratio. When the average thickness of coating achieved at 106 μm, the limit oxygen index value of ABS...