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Molecular ribbons (MRs), one‐dimentional topological polycyclic aromatic hydrocarbons (PAHs), are of importance for synthetic chemistry and material sciences. Herein, we disclose an effective strategy to develop boron‐doped MRs, i.e. photochemical cyclization on conjugated organoboranes for rapid π‐extension. A series of ribbon‐type boron‐doped PAHs that own multiple cove edges were synthesized using...
Molecular ribbons (MRs), one‐dimentional topological polycyclic aromatic hydrocarbons (PAHs), are of importance for synthetic chemistry and material sciences. Herein, we disclose an effective strategy to develop boron‐doped MRs, i.e. photochemical cyclization on conjugated organoboranes for rapid π‐extension. A series of ribbon‐type boron‐doped PAHs that own multiple cove edges were synthesized using...