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The self-organization of polyhedral silsesquioxane (POSS) moieties tethered as side groups onto flexible backbones of amorphous siloxanes and poly(1,2-butadiene) was investigated. For comparison, linear oligosiloxanes substituted with POSS units at the chain end (α- or α,ω-functionalization) were examined. The properties of POSS-functionalized materials were studied (SAXS, WAXD, DSC, TGA, and optical...
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