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In the present work, we report synthesis of new zirconium complex supported on mesoporous silica by anchoring of adenine on the wall of functionalized MCM‐41, then reacted with ZrOCl2. The resultant MCM‐41‐Adenine‐Zr was characterized by FT‐IR, XRD, TEM, SEM, TGA, EDX, ICP and BET techniques. It was exhibited that the MCM‐41‐Adenine‐Zr can be used as an efficient and thermally stable nanocatalyst...
The novel title compounds, (pipzH 2 ) 1.5 (pydcH) 3 ·3.7H 2 O, 1, (pipzH 2 )[Zr(pydc) 3 ]·8H 2 O, 2 and (pipzH 2 )[Ce(pydc) 3 ]·8H 2 O, 3 in which pydcH 2 is pyridine-2,6-dicarboxylic acid and pipz is piperazine were obtained in aqueous solution. The compounds were characterized by IR, 1 H NMR and 13...
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