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Während goldkatalysierte synergistische katalytische Prozesse, die Transmetallierung mit anderen Metallen einbeziehen, gut verstanden sind, sind AuI/AuIII‐Zyklen in diesen Reaktionen sehr selten. Hier wird eine goldkatalysierte direkte Alkinylierung von Cyclopropenen über zwei aktive Katalysezyklen ermöglicht, ein oxidativer Katalysezyklus mit einem über oxidative Addition gebildeten Alkinyl‐AuIII...
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