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An initial Coulombic efficiency (ICE) higher than 90% is crucial for industrial lithium‐ion batteries, but numerous electrode materials are not standards compliant. Lithium trapping, due to i) incomplete solid‐state reaction of Li+ generation and ii) sluggish Li+ diffusion, undermines ICE in high‐capacity electrodes (e.g., conversion‐type electrodes). Current approaches mitigating lithium trapping...
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