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A novel phase transition, from multilayered 2H‐MoTe2 to a parallel bundle of sub‐nanometer‐diameter metallic Mo6Te6 nanowires (NWs) driven by catalyzer‐free thermal‐activation (400–500 °C) under vacuum, is demonstrated. The NWs form along the 〈11–20〉 2H‐MoTe2 crystallographic directions with lengths in the micrometer range. The metallic NWs can act as an efficient hole injection layer on top of 2H‐MoTe...
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