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Transition metal‐catalyzed C−S cross‐coupling has emerged as an important strategy to furnish thioethers; however, the dominant utilization of noble metal catalysts as well as the construction of challenging C(sp3)−S bonds by transition metal‐catalysis remain highly problematic. Earth‐abundant manganese has gathered increasing interest as an attractive catalyst for new reaction development; nevertheless,...
Transition metal‐catalyzed C−S cross‐coupling has emerged as an important strategy to furnish thioethers; however, the dominant utilization of noble metal catalysts as well as the construction of challenging C(sp3)−S bonds by transition metal‐catalysis remain highly problematic. Earth‐abundant manganese has gathered increasing interest as an attractive catalyst for new reaction development; nevertheless,...